Amino and triazole-containing metal-organic frameworks for highly efficient CO<sub>2</sub> fixation.

Li, Yang; Tian, Xueqin; Jiang, Weiwei; Wu, Pengyan; Li, Han-Shu; Wang, Man; Lin, Chen; Wang, Jian

Amino and triazole-containing metal-organic frameworks for highly efficient CO₂ fixation.

Li, Yang; Tian, Xueqin; Jiang, Weiwei; Wu, Pengyan; Li, Han-Shu; Wang, Man; Lin, Chen; Wang, Jian.

Afiliación

Li Y; School of Chemistry and Materials Science & Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China. wpyan@jsnu.edu.cn.
Tian X; School of Chemistry and Materials Science & Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China. wpyan@jsnu.edu.cn.
Jiang W; School of Chemistry and Materials Science & Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China. wpyan@jsnu.edu.cn.
Wu P; School of Chemistry and Materials Science & Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China. wpyan@jsnu.edu.cn.
Li HS; School of Chemistry and Materials Science & Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China. wpyan@jsnu.edu.cn.
Wang M; School of Chemistry and Materials Science & Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China. wpyan@jsnu.edu.cn.
Lin C; School of Chemistry and Materials Science & Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China. wpyan@jsnu.edu.cn.
Wang J; School of Chemistry and Materials Science & Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, China. wpyan@jsnu.edu.cn.

Chem Commun (Camb) ; 57(82): 10803-10806, 2021 Oct 14.

Article en En | MEDLINE | ID: mdl-34590631

ABSTRACT

ABSTRACT

In this study, a novel porous metal-organic framework (MOF) functionalized with amino and triazole moieties has been synthesized. Attributed to the high affinity to CO2 and unsaturated zinc centers, the MOF exhibits high catalytic activity for the CO2 to epoxide cycloaddition reaction, with a turnover number value of up to 10 000 per cycle, and can be reused at least for 20 cycles.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: China

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