Derivatization of an especially electron-rich diborane.
Chem Commun (Camb)
; 58(5): 693-696, 2022 Jan 13.
Article
en En
| MEDLINE
| ID: mdl-34920449
ABSTRACT
Starting with electron-rich ditriflato-diborane B2(hpp)2(OTf)2 (hpp = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-α]pyrimidinate), novel symmetric and unsymmetric diboranes B2(hpp)2X2 and B2(hpp)2XY with X,Y = Br, NCS, N3 or OTf are synthesized by substitution reactions with SN1 mechanisms. The stability of the unsymmetric diboranes with respect to dismutation equilibria is evaluated.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2022
Tipo del documento:
Article
País de afiliación:
Alemania