C-H bond chlorination using nickel(II) complexes of tetradentate amido-quinoline ligands.
Chem Commun (Camb)
; 58(25): 4075-4078, 2022 Mar 24.
Article
en En
| MEDLINE
| ID: mdl-35265952
ABSTRACT
Ni(II)-tetradentate amido-quinoline complexes effectively catalysed C-H chlorination of a series of hydrocarbons in the presence of NaOCl and acetic acid. The bond dissociation energy of the C(sp3)-H bond of the substrates varies from 99.3 kcal mol-1 (cyclohexane) to 87 kcal mol-1 (ethyl benzene). Exclusively chlorinated products (TON 220 for cyclohexane) were obtained without any hydroxylated products, thus mimicking the activity of the halogenase enzyme.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Quinolinas
/
Níquel
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2022
Tipo del documento:
Article
País de afiliación:
India