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A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope.
Maliszewski, Benon P; Ritacco, Ida; Belis, Marek; Hashim, Ishfaq Ibni; Tzouras, Nikolaos V; Caporaso, Lucia; Cavallo, Luigi; Van Hecke, Kristof; Nahra, Fady; Cazin, Catherine S J; Nolan, Steven P.
Afiliación
  • Maliszewski BP; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium. steven.nolan@ugent.be.
  • Ritacco I; VITO (Flemish Institute for Technological Research), Separation and Conversion Technology, Boeretang 200, 2400 Mol, Belgium.
  • Belis M; Dipartimento di Chimica e Biologia, Univeristy of Salerno, Via Papa Paolo Giovanni II, Fisciano, I-84084, Italy.
  • Hashim II; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium. steven.nolan@ugent.be.
  • Tzouras NV; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium. steven.nolan@ugent.be.
  • Caporaso L; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium. steven.nolan@ugent.be.
  • Cavallo L; Dipartimento di Chimica e Biologia, Univeristy of Salerno, Via Papa Paolo Giovanni II, Fisciano, I-84084, Italy.
  • Van Hecke K; KAUST Catalysis Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia.
  • Nahra F; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium. steven.nolan@ugent.be.
  • Cazin CSJ; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium. steven.nolan@ugent.be.
  • Nolan SP; VITO (Flemish Institute for Technological Research), Separation and Conversion Technology, Boeretang 200, 2400 Mol, Belgium.
Dalton Trans ; 51(16): 6204-6211, 2022 Apr 20.
Article en En | MEDLINE | ID: mdl-35357386
ABSTRACT
A sustainable and facile weak-base synthetic route to platinum N-heterocyclic carbene (NHC) complexes is disclosed. The mechanism of this reaction is also elucidated via experimental and computational investigations. This straightforward protocol is then used for the synthesis of novel Pt(II)-NHC complexes and its utility is further explored to access key Pt(0)-NHC precatalysts.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Bélgica
Texto completo
Añadir a Mi BVS
Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Bélgica