Adsorption effect and the removal mechanism of silicate composite biochar particles on cadmium in soil.

Ordinary biochar has the disadvantages of low strength and fragility, and it is difficult to be separated in heavy metal contaminated soil after the remediation process. In order to realize the recovery and reuse of biochar, we prepared silicate composite biochar (SCB) and the magnetic silicate composite biochar (MSCB) with consistent particle size and high hardness. As well as the passivation effect and mechanism of the material on cadmium in soil was also investigated. The results showed that: (1) The MSCB had good hydraulic properties and strong magnetism, which can be quickly separated from the soil under the condition of external magnetic field. (2) The MSCB can remove 30.32%-38.80% of cadmium in the soil after three times of "application-separation-desorption-reuse", as well as the SCB can remove 28.30%-35.78% of cadmium from the soil. (3) The recovered SCB and MSCB had a certain mass loss, the mass loss rate of the biochar particles was in the range of 2.65%-4.90% after each time of recycling. (4) MSCB mainly immobilized cadmium ions through pore interception, complexation of oxygen-containin/iron-containin functional group and precipitation reaction.