A lamellar V2O3@C composite for aluminium-ion batteries displaying long cycle life and low-temperature tolerance.
Chem Commun (Camb)
; 58(51): 7172-7175, 2022 Jun 23.
Article
en En
| MEDLINE
| ID: mdl-35670315
ABSTRACT
Rechargeable aluminum-ion (Al-ion) batteries have important potential for fast charging and safe energy-storage systems. Here, we develop a composite composed of lamellar V2O3@C nanosheets, which displays high electrochemical properties as an Al-ion battery cathode. The unique structure is conducive to the rapid insertion and release of Al3+ ions, electrolyte infiltration, and improved conductivity. After cycling 500 times, the capacity exceeds 242.5 mA h g-1. Under a low temperature of -10 °C, the capacity remains 150.8 mA h g-1, and the Coulombic efficiency is higher than 98.8%. The V2O3@C also exhibits a good reversibility verified by using ex situ X-ray powder diffraction patterns, while the constant current intermittent titration technology shows a low reaction barrier, which indicates that the lamellar composite presented here could find significant applications for engineering many high-performance energy-storage systems.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2022
Tipo del documento:
Article