Green calcium-based photocatalyst derived from waste marble powder for environmental sustainability: A review on synthesis and application in photocatalysis.

Calcium, with its excellent adsorptive property and higher permissible limits in the environment, emerges as an effective wastewater treatment earth metal. Most of the catalysts, photocatalysts, and adsorbents reported in the literature have heavy metal complex, which creates a leaching problem. Majorly, precursors used for the synthesis of heterogeneous catalysts for wastewater treatment are costly. Therefore, the use of such precursors would be not suitable and feasible approach from an economic point of view. This review work is focused on giving an overview of the utilisation of calcium-based catalysts (adsorbents and photocatalyst) for the removal/degradation of various types of dye water pollutants and summarises the reported effects of calcium as a base on the removal efficiency of dopants. In this article, an extensive literature survey is presented on the various photocatalysts developed and the different syntheses involved in their preparation. As the utilisation of marble powder is a green sustainable approach, the scope of various calcium-based photocatalysts and their application is presented. This article also aims for the elementary and inclusive determination of the effect of introducing calcium as a base for different catalysts and adsorbents.