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Copper-assisted trifluoromethylthiolation/radical cascade cyclization of alkynes to construct SCF3-containing dioxodibenzothiazepines.
Chen, Xiaoyu; Pei, Congcong; Liu, Bo; Li, Jingya; Zou, Dapeng; Wu, Yangjie; Wu, Yusheng.
Afiliación
  • Chen X; College of Chemistry, Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001, People's Republic of China. zdp@zzu.edu.cn.
  • Pei C; College of Chemistry, Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001, People's Republic of China. zdp@zzu.edu.cn.
  • Liu B; College of Chemistry, Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001, People's Republic of China. zdp@zzu.edu.cn.
  • Li J; Tetranov Biopharm, LLC., Zhengzhou, 450052, People's Republic of China.
  • Zou D; College of Chemistry, Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001, People's Republic of China. zdp@zzu.edu.cn.
  • Wu Y; College of Chemistry, Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001, People's Republic of China. zdp@zzu.edu.cn.
  • Wu Y; College of Chemistry, Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001, People's Republic of China. zdp@zzu.edu.cn.
Chem Commun (Camb) ; 58(62): 8674-8677, 2022 Aug 02.
Article en En | MEDLINE | ID: mdl-35822922
ABSTRACT
A mild and efficient Cu-assisted trifluoromethylthiolation/radical cascade cyclization of alkynes with readily available and stable AgSCF3 as the trifluoromethylthiolating reagent has been disclosed. This transformation provides an opportunity to construct a series of potential medicinally valuable trifluoromethylthio-substituted dioxodibenzothiazepines with wide functional group compatibility. This protocol opens up a new avenue for the construction of useful trifluoromethylthiolated seven-membered N-heterocycles.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Cobre / Alquinos Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Cobre / Alquinos Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article