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Synthesis of the two isomers of heteroleptic Rh12L6L'6 metal-organic polyhedra by screening of complementary linkers.
Broto-Ribas, Anna; Gutiérrez, María Susana; Imaz, Inhar; Carné-Sánchez, Arnau; Gándara, Felipe; Juanhuix, Judith; Maspoch, Daniel.
Afiliación
  • Broto-Ribas A; Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, 08193 Bellaterra, Barcelona, Spain. inhar.imaz@icn2.cat.
  • Gutiérrez MS; Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193, Bellaterra, Spain.
  • Imaz I; Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, 08193 Bellaterra, Barcelona, Spain. inhar.imaz@icn2.cat.
  • Carné-Sánchez A; Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193, Bellaterra, Spain.
  • Gándara F; Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, 08193 Bellaterra, Barcelona, Spain. inhar.imaz@icn2.cat.
  • Juanhuix J; Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193, Bellaterra, Spain.
  • Maspoch D; Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, 08193 Bellaterra, Barcelona, Spain. inhar.imaz@icn2.cat.
Chem Commun (Camb) ; 58(75): 10480-10483, 2022 Sep 20.
Article en En | MEDLINE | ID: mdl-35880835
We have synthesised and characterised the two possible isomers of heteroleptic trigonal antiprismatic M12L6L'6 MOPs by screening reactions of rhodium acetate with different pairs of complementary dicarboxylate linkers. The resulting 12 new MOPs (eight of isomer A + four of isomer B) are microporous in the solid state, exhibiting Brunauer-Emmett-Teller (BET) surface areas as high as 770 m2 g-1.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Diagnostic_studies / Screening_studies Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: España Pais de publicación: Reino Unido
Texto completo
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Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Diagnostic_studies / Screening_studies Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: España Pais de publicación: Reino Unido