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Plasmonic Ag-decorated Cu2O nanowires for boosting photoelectrochemical CO2 reduction to multi-carbon products.
Zhang, Yanfang; Wang, Qingmei; Wang, Keke; Liu, Yang; Zou, Luwei; Zhou, Yu; Liu, Min; Qiu, Xiaoqing; Li, Wenzhang; Li, Jie.
Afiliación
  • Zhang Y; School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China. liwenzhang@csu.edu.cn.
  • Wang Q; School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China. liwenzhang@csu.edu.cn.
  • Wang K; School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China. liwenzhang@csu.edu.cn.
  • Liu Y; School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China. liwenzhang@csu.edu.cn.
  • Zou L; School of Physics and Electronics, Central South University, Changsha 410083, China.
  • Zhou Y; School of Physics and Electronics, Central South University, Changsha 410083, China.
  • Liu M; School of Physics and Electronics, Central South University, Changsha 410083, China.
  • Qiu X; School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China. liwenzhang@csu.edu.cn.
  • Li W; School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China. liwenzhang@csu.edu.cn.
  • Li J; Hunan Provincial Key Laboratory of Chemical Power Sources, Central South University, Changsha, 410083, China.
Chem Commun (Camb) ; 58(67): 9421-9424, 2022 Aug 18.
Article en En | MEDLINE | ID: mdl-35916216
ABSTRACT
The generation of multi-carbon products on the Cu2O photocathode remains a great challenge. Herein, effective charge separation and surface catalytic reaction are achieved for photoelectrochemical CO2 reduction through plasmon metal (Ag) decoration on Cu2O nanowires. The Cu2O/Ag composite photocathode achieves a 47.7% faradaic efficiency for CH3COOH and the generation rate is 212.7 µmol cm-2 h-1 under illumination, which is about five times that in dark (44.4 µmol cm-2 h-1) at -0.7 V vs. RHE.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: China

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: China