Stereomodulation of Poly(4-methyl-1-pentene): Adoption of a Neglected and Misunderstood Commercial Polyolefin.
Angew Chem Int Ed Engl
; 61(45): e202211992, 2022 Nov 07.
Article
en En
| MEDLINE
| ID: mdl-36101919
ABSTRACT
A toolbox of living coordination polymerization methods based on CPAM group 4 metal initiators has been applied for the stereomodulation of poly(4-methyl-1-pentene) (PMP) tacticity to provide new fundamental forms in which thermal phase transitions, Tg and Tm , can be adjusted over a wide range. Also reported for the first time are the synthesis and properties of authenticated 1,2-regioregular atactic PMP, which serves to correct past errors regarding this fundamental polyolefin.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2022
Tipo del documento:
Article
País de afiliación:
Estados Unidos