Speed Tuning of the Formation/Dissociation of a Metallorotaxane.
Angew Chem Int Ed Engl
; 62(11): e202217048, 2023 Mar 06.
Article
en En
| MEDLINE
| ID: mdl-36628483
ABSTRACT
Switching between the formation/dissociation of rotaxanes is important to control the function of various types of rotaxane-based materials. We have developed a convenient and simple strategy, the so-called "accelerator addition", to make a static rotaxane dynamic without apparently affecting the chemical structure. As an interlocked molecule that enables tuning of the formation/dissociation speed, a metallorotaxane was quantitatively generated by the complexation of a triptycene-based dumbbell-shaped mononuclear complex, [PdL2 ]2+ (L=2,3-diaminotriptycene), with 27C9. As a result of the inertness of the Pd2+ -based coordination structure, the metallorotaxane was slowly formed (the static state). This rotaxane formation was accelerated 27â
times simply by adding Br- as an accelerator (the dynamic state). A similar drastic acceleration was also demonstrated during the dissociation process when Cs+ was added to the metallorotaxane to form the free axle [PdL2 ]2+ and the 27C9-Cs+ complex.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2023
Tipo del documento:
Article
País de afiliación:
Japón