Extending the Hammett correlation to mechanochemical reactions.

Vugrin, Leonarda; Carta, Maria; Delogu, Francesco; Halasz, Ivan

Vugrin, Leonarda; Carta, Maria; Delogu, Francesco; Halasz, Ivan.

Afiliación

Vugrin L; Ruder Boskovic Institute, Bijenicka c. 54, Zagreb 10000, Croatia. ivan.halasz@irb.hr.
Carta M; Department of Mechanical, Chemical and Materials Engineering, University of Cagliari, via Marengo 2, Cagliari 09123, Italy. francesco.delogu@unica.it.
Delogu F; Department of Mechanical, Chemical and Materials Engineering, University of Cagliari, via Marengo 2, Cagliari 09123, Italy. francesco.delogu@unica.it.
Halasz I; Ruder Boskovic Institute, Bijenicka c. 54, Zagreb 10000, Croatia. ivan.halasz@irb.hr.

Chem Commun (Camb) ; 59(12): 1629-1632, 2023 Feb 07.

Article en En | MEDLINE | ID: mdl-36662170

ABSTRACT

ABSTRACT

Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical-organic chemistry could be transferable to ball milling reactions in the solid state.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article País de afiliación: Croacia

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