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Asymmetric Friedel-Crafts-Type Reaction of 2-Vinylindoles to N-Boc Imines Using a Chiral Imidazolidine-Containing NCN-Pincer Pd Catalyst.
Yokota, Tomoya; Masu, Hyuma; Arai, Takayoshi.
Afiliación
  • Yokota T; Soft Molecular Activation Research Center (SMARC), Chiba Iodine Resource Innovation Center (CIRIC), Synthetic Organic Chemistry, Department of Chemistry, Graduate School of Science, Chiba University, 1-33 Yayoi, Inage, Chiba, Chiba 263-8522, Japan.
  • Masu H; Center for Analytical Instrumentation, Chiba University, 1-33 Yayoi, Inage, Chiba, Chiba 263-8522, Japan.
  • Arai T; Soft Molecular Activation Research Center (SMARC), Chiba Iodine Resource Innovation Center (CIRIC), Synthetic Organic Chemistry, Department of Chemistry, Graduate School of Science, Chiba University, 1-33 Yayoi, Inage, Chiba, Chiba 263-8522, Japan.
J Org Chem ; 88(12): 7872-7881, 2023 Jun 16.
Article en En | MEDLINE | ID: mdl-36802597
ABSTRACT
A chiral imidazolidine-containing NCN-pincer Pd-OTf complex (NCN-Pd cat) promoted the asymmetric nucleophilic addition of unprotected 2-vinylindoles to N-Boc imines in a Friedel-Crafts-type manner. The chiral (2-vinyl-1H-indol-3-yl)methanamine products become nice platforms for constructing multiple ring systems.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Imidazolidinas / Indoles Idioma: En Revista: J Org Chem Año: 2023 Tipo del documento: Article País de afiliación: Japón
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Imidazolidinas / Indoles Idioma: En Revista: J Org Chem Año: 2023 Tipo del documento: Article País de afiliación: Japón