Asymmetrical Dependence of {Ba2+}:{SO4 2-} on BaSO4 Crystal Nucleation and Growth in Aqueous Solutions: A Dynamic Light Scattering Study.
ACS Omega
; 8(6): 5760-5775, 2023 Feb 14.
Article
en En
| MEDLINE
| ID: mdl-36816709
ABSTRACT
The impact of solution stoichiometry, upon formation of BaSO4 crystals in 0.02 M NaCl suspensions, on the development of particle size was investigated using dynamic light scattering (DLS). Measurements were performed on a set of suspensions prepared with predefined initial supersaturation, based on the quotient of the constituent ion activity product {Ba2+}{SO4 2-} over the solubility product K sp (Ωbarite = {Ba2+}{SO4 2-}/K sp = 100, 500, or 1000-11,000 in steps of 1000), and ion activity solution stoichiometries (r aq = {Ba2+}{SO4 2-} = 0.01, 0.1, 1, 10 and 100), at circumneutral pH of 5.5-6.0, and ambient temperature and pressure. DLS showed that for batch experiments, crystal formation with varying r aq was best investigated at an initial Ωbarite of 1000 and using the forward detection angle. At this Ωbarite and set of r aq, the average apparent hydrodynamic particle size of the largest population present in all suspensions increased from â¼200 to â¼700 nm within 10-15 min and was independently confirmed by transmission electron microscopy (TEM) imaging. Additional DLS measurements conducted at the same conditions in flow confirmed that the BaSO4 formation kinetics were very fast for our specifically chosen conditions. The DLS flow measurements, monitoring the first minute of BaSO4 formation, showed strong signs of aggregation of prenucleation clusters forming particles with a size in the range of 200-300 nm for every r aq. The estimated initial bulk growth rates from batch DLS results show that BaSO4 crystals formed fastest at near-stoichiometric conditions and more slowly at nonstoichiometric conditions. Moreover, at extreme SO4-limiting conditions, barite formation was slower compared to Ba-limiting conditions. Our results show that DLS can be used to investigate nucleation and growth at carefully selected experimental and analytical conditions. The combined DLS and TEM results imply that BaSO4 formation is influenced by solution stoichiometry and may aid to optimize antiscalant efficiency and regulate BaSO4 (scale) formation processes.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
ACS Omega
Año:
2023
Tipo del documento:
Article
País de afiliación:
Países Bajos