Improved photovoltaic performance of Pb-free AgBi2I7 based photovoltaics.
Nanoscale Adv
; 5(6): 1624-1630, 2023 Mar 14.
Article
en En
| MEDLINE
| ID: mdl-36926577
ABSTRACT
Hybrid perovskites based on bismuth are good candidates for developing lead-free and air-stable photovoltaics, but they have historically been constrained by poor surface morphologies and large band-gap energies. Monovalent silver cations are incorporated into iodobismuthates as part of a novel materials processing method to fabricate improved bismuth-based thin-film photovoltaic absorbers. However, a number of fundamental characteristics prevented them from achieving better efficiency. We examine bismuth iodide perovskite made of silver with improvements in surface morphology and a narrow band gap, and we achieve high power conversion efficiency. AgBi2I7 perovskite was used in the fabrication of PSCs as a material for light absorption, and its optoelectronic proficiencies were also studied. We reduced the band gap to 1.89 eV and achieved a maximum power conversion efficiency of 0.96% using the solvent engineering approach. Additionally, simulation studies verified an efficiency of 13.26% by using AgBi2I7 as a light absorber perovskite material.
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MEDLINE
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En
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Nanoscale Adv
Año:
2023
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Article