Tunable vicinal, geminal diphosphorylation and C-N bond phosphorylation of enaminones toward divergent phosphorylated ketone derivatives.
Chem Commun (Camb)
; 59(42): 6383-6386, 2023 May 23.
Article
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| MEDLINE
| ID: mdl-37157911
ABSTRACT
This paper reports the trifunctionalization reactions of tertiary enaminones in the fashion of selective gem- and vicinal diphosphorylation, leading to the tunable synthesis of α,α- and α,ß-diphosphoryl ketones. In addition, the C-N bond phosphorylation with improved substrate tolerance has been achieved.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2023
Tipo del documento:
Article
País de afiliación:
China