Effect of surface functional groups on MXene conductivity.
J Chem Phys
; 158(19)2023 May 21.
Article
en En
| MEDLINE
| ID: mdl-37184011
ABSTRACT
We report the in-plane electron transport in the MXenes (i.e., within the MXene layers) as a function of composition using the density-functional tight-binding method, in conjunction with the non-equilibrium Green's functions technique. Our study reveals that all MXene compositions have a linear relationship between current and voltage at lower potentials, indicating their metallic character. However, the magnitude of the current at a given voltage (conductivity) has different trends among different compositions. For example, MXenes without any surface terminations (Ti3C2) exhibit higher conductivity compared to MXenes with surface functionalization. Among the MXenes with -O and -OH termination, those with -O surface termination have lower conductivity than the ones with -OH surface terminations. Interestingly, conductivity changes with the ratio of -O and -OH on the MXene surface. Our calculated I-V curves and their conductivities correlate well with transmission functions and the electronic density of states around the Fermi level. The surface composition-dependent conductivity of the MXenes provides a path to tune the in-plane conductivity for enhanced pseudocapacitive performance.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Chem Phys
Año:
2023
Tipo del documento:
Article
País de afiliación:
Estados Unidos