Redox flexibility in a germanium hydride manifold: hydrogen shuttling via oxidative addition and reductive elimination.
Chem Commun (Camb)
; 59(47): 7251-7254, 2023 Jun 08.
Article
en En
| MEDLINE
| ID: mdl-37222547
ABSTRACT
We report the synthesis of a trimetallic mixed-valence Ge(I)/Ge(II)/Ge(III) trihydride, which presents a structural novel motif among systems of the type (XMH)n (M = group 14 metal). In terms of reactivity (ArNiPr2)GeGe(ArNiPr2)(H)Ge(ArNiPr2)(H)2 can act as a source of both the Ge(II) and Ge(IV) hydrides via Ge-H reductive elimination from the central metal centre involving two different regiochemistries.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Germanio
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2023
Tipo del documento:
Article
País de afiliación:
Reino Unido