Probing the surface-active sites of metal nanoclusters with atomic precision: a case study of Au5Ag11.
Nanoscale
; 15(33): 13784-13789, 2023 Aug 25.
Article
en En
| MEDLINE
| ID: mdl-37578144
ABSTRACT
The determination of surface-active sites in metal nanoclusters is of great significance for the in-depth understanding of structural evolutions and physicochemical property mechanisms. In this work, the surface-active sites of the Au5Ag11(DMBT)8(DPPOE)2 cluster template towards metal-/ligand-exchange reactions were unambiguously identified at the atomic level. The active-site tailoring of this nanocluster gave rise to three derivative nanoclusters, Au5Ag9Cu2(DMBT)8(DPPOE)2, Au5Ag11(DMBT)6(DCBT)2(DPPOE)2, and Au5Ag11(DCBT)8(DPPOE)2. The single-crystal structural analysis revealed that all these M16 (M = Au/Ag/Cu) clusters exhibited almost the same framework. Besides, the surface-active site tailoring contributed to significant changes in optical absorptions and emissions of these metal nanoclusters. The findings in this work not only provide an in-depth understanding of the active-site tailoring of cluster surface structures but also develop an intriguing template that enables us to grasp the structure-property correlations at the atomic level.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Tipo de estudio:
Prognostic_studies
Idioma:
En
Revista:
Nanoscale
Año:
2023
Tipo del documento:
Article