Gels of Semiconducting Polymers in Benign Solvents.
Langmuir
; 39(35): 12283-12291, 2023 Sep 05.
Article
en En
| MEDLINE
| ID: mdl-37611231
ABSTRACT
Gels of semiconducting polymers have many potential applications, including biomedical devices and sensors. Here, we report a self-assembled gel system consisting of isoindigo-based semiconducting polymers with galactose side chains in benign, alcohol-based solvents. Because of the carbohydrate side chains, the modified isoindigo polymers are soluble in alcohols. We obtained thermoreversible gels in 1-propanol using these polymers and di-Fmoc-l-lysine, a molecular gelator. The polymers and molecular gelators have been selected in such a way that they do not have significant physical interactions. The molecular gelator self-assembled to form a fibrous structure that confines the polymer chains in the interstitial spaces of the fibers. The polymer chains formed local aggregations and increased the shear moduli of the gels significantly. Bulky galactose side chains and the less planar nature of the polymer backbone hindered the formation of long-range assembled structures of the polymers. However, the dispersion of polymers throughout the gel samples resulted in a percolated structure in the dried gel films. The bulk electrical conductivity of dried gels confirmed the presence of such percolated structures. Our results demonstrated that carbohydrate-containing conjugated polymers can be combined with molecular gelators to obtain gels in eco-friendly solvents.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Langmuir
Asunto de la revista:
QUIMICA
Año:
2023
Tipo del documento:
Article
País de afiliación:
Estados Unidos