Synthetically Useful Transformations of Olefins via Cationic 1,2-Oxazetium Intermediates.

Reddy, G Sudhakar; Corey, E J

Reddy, G Sudhakar; Corey, E J.

Afiliación

Reddy GS; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.
Corey EJ; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.

Org Lett ; 25(39): 7160-7164, 2023 Oct 06.

Article en En | MEDLINE | ID: mdl-37734041

RESUMEN

Nitrosyl triflate serves as a NO+ donor in reactions with many olefinic substrates to form reactive, cationic 1,2-oxazetium cycloadducts that can be converted selectively into a wide range of useful products depending on reagents and conditions.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2023 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

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