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Multinary nanocomposite of GO@SrO@CoCrO3@FeCr2O4@SnO2@SiO2 for superior electrochemical performance and water purification applications.
Batool, Kiran; Rani, Malika; Rasool, Faisal; Karami, Abdulnasser M; Sillanpää, Mika; Shafique, Rubia; Akram, Mariam; Sohail, Amir.
Afiliación
  • Batool K; Department of Physics, The Women University, P.O. Box 66000, Multan, Pakistan.
  • Rani M; Department of Physics, The Women University, P.O. Box 66000, Multan, Pakistan.
  • Rasool F; Department of Chemistry, Khalifa University of Science and Technology, Abu Dhabi, 127788, United Arab Emirates.
  • Karami AM; Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia.
  • Sillanpää M; Department of Biological and Chemical Engineering, Aarhus University, Norrebrogade 44, 8000, Aarhus C, Denmark.
  • Shafique R; Department of Physics, The Women University, P.O. Box 66000, Multan, Pakistan.
  • Akram M; Department of Physics, The Women University, P.O. Box 66000, Multan, Pakistan.
  • Sohail A; Department of Chemistry, University of Otago, Dunedin, 9016, New Zealand.
Heliyon ; 9(10): e20675, 2023 Oct.
Article en En | MEDLINE | ID: mdl-37842602
Novel multinary nanocomposite using solvothermal method synthesized and studied for their use in supercapacitors and photocatalysis to degrade pollutants using characterization techniques XRD, SEM, EDX, FTIR, Raman, UV-Vis, Zeta potential and photoluminescence spectroscopy whereas electrochemical testing via EIS, CV and GCD analysis. Average crystalline size of 20.81 nm measured from XRD whereas EDX confirms GO suppression within nanocomposite. Mixed matrix like morphology is observable from SEM micrographs. The composite exhibited a band gap of 2.78 eV that could degrade MB dye at 94 % under direct sunlight consistent with first-order kinetics. Multiple distinctive peaks in FTIR spectra indicates various functional groups exsistence in the material alongwith zeta potential value of -17.9 mV. Raman spectra reveals D-band shifting to value 1361 cm-1 while the G-band shifts to 1598 cm-1 relative to GO. Furthermore electrochemical performance evaluated revealing electron transfer rate value 4.88 × 10-9 cms-1 with maximum capacitance about 7182 Fg-1 at a scan rate of 10 mVs-1 respectively. Power density ranges from 3591.18 to 2163 W/kg and energy density from 299 to 120 Wh/Kg as measured from GCD analysis. These findings indicates that novel multinary nanocomposite holds potential as an electrode material in supercapacitors and as a sunlight-driven photocatalyst for the degradation of water-borne organic pollutants.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Heliyon Año: 2023 Tipo del documento: Article País de afiliación: Pakistán Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Heliyon Año: 2023 Tipo del documento: Article País de afiliación: Pakistán Pais de publicación: Reino Unido