Advanced capacitive deionization for ion selective separation: Insights into mechanism over a functional classification.
Chemosphere
; 346: 140601, 2024 Jan.
Article
en En
| MEDLINE
| ID: mdl-37918536
ABSTRACT
Due to the diversity and variability of harmful ions in polluted water bodies, the selective removal and separation for specific ions is of great significance in water purification and resource processes. Capacitive deionization (CDI), an emerging desalination technology, shows great potential to selectively remove harmful ionic pollutants and further recover valuable ions because of the simple operation and low energy consumption. Researchers have done a lot of work to investigate ion selectivity utilizing CDI, including both theoretical and experimental studies. Nevertheless, in the investigation of selective mechanisms, phenomena where carbon materials exhibit entirely opposite selectivity require further analysis. Furthermore, there is a need to summarize the specific chemical reaction mechanisms, including the formation of hydrogen bonds, complexation reactions, and ligand exchanges, within selective electrodes, which have not been thoroughly examined in detail previously. In order to fill these gaps, in this review, we summarized the recent progress of CDI technologies for ion selective separation, and explored the selective separation mechanism of CDI from three aspects selective physical adsorption, specific chemical reaction, and the utilization of selective barriers. Additionally, this review analyzes in detail the formation process of chemical bonds and ion conversion pathways when ions interact with electrode materials. Finally, some significant development prospects and challenges were offered for the future selective CDI systems. We believe the review will provide new insights for researchers in the field of ion selective separation.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Carbono
/
Purificación del Agua
Idioma:
En
Revista:
Chemosphere
Año:
2024
Tipo del documento:
Article
País de afiliación:
China