Your browser doesn't support javascript.
loading
Evolution of a 'privileged' P-alkene ligand: added planar chirality beats BINOL axial chirality in catalytic asymmetric C-C bond formation.
Leinauer, Luisa; Parla, Giorgio; Messelbeger, Julian; Herrera, Alberto; Heinemann, Frank W; Langer, Jens; Chuchelkin, Ilya; Grasruck, Alexander; Frieß, Sibylle; Chelouan, Ahmed; Gavrilov, Konstantin; Dorta, Romano.
Afiliación
  • Leinauer L; Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany. romano.dorta@fau.de.
  • Parla G; Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany. romano.dorta@fau.de.
  • Messelbeger J; Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany. romano.dorta@fau.de.
  • Herrera A; Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany. romano.dorta@fau.de.
  • Heinemann FW; Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany. romano.dorta@fau.de.
  • Langer J; Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany. romano.dorta@fau.de.
  • Chuchelkin I; Department of Chemistry, Ryazan State University Named after S. Yesenin, 46 Svoboda Street, 390000 Ryazan, Russian Federation.
  • Grasruck A; Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany. romano.dorta@fau.de.
  • Frieß S; Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany. romano.dorta@fau.de.
  • Chelouan A; Department of Chemistry, Abdelmalek Essaadi University, B.P. 2121, 39, Hannech II, 93002 Tétouan, Morocco.
  • Gavrilov K; Department of Chemistry, Ryazan State University Named after S. Yesenin, 46 Svoboda Street, 390000 Ryazan, Russian Federation.
  • Dorta R; Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany. romano.dorta@fau.de.
Chem Commun (Camb) ; 59(97): 14451-14454, 2023 Dec 05.
Article en En | MEDLINE | ID: mdl-37982441
ABSTRACT
Alkene planar chirality is introduced in the 'privileged' P-alkene phosphoramidite ligand 1. The resulting diastereomeric ligands (pR,R)-5 and (pS,R)-5 form optically pure complexes of Rh(I) and Pd(II), which catalyze conjugate additions of boron C-nucleophiles to enones and allylic alkylations, respectively. In the Rh-catalyzed reaction, the planar chirality of the alkene exerts absolute enantiocontrol over the potent BINOL auxiliary.
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article País de afiliación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article País de afiliación: Alemania