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Instantons and the quantum bound to chaos.
Sadhasivam, Vijay Ganesh; Meuser, Lars; Reichman, David R; Althorpe, Stuart C.
Afiliación
  • Sadhasivam VG; Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, United Kingdom.
  • Meuser L; Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, United Kingdom.
  • Reichman DR; Department of Chemistry and Applied Biosciences, ETH Zurich (Swiss Federal Institute of Technology), Zürich 8093, Switzerland.
  • Althorpe SC; Department of Chemistry, Columbia University, New York, NY 10027.
Proc Natl Acad Sci U S A ; 120(49): e2312378120, 2023 Dec 05.
Article en En | MEDLINE | ID: mdl-38032936
ABSTRACT
The rate at which information scrambles in a quantum system can be quantified using out-of-time-ordered correlators. A remarkable prediction is that the associated Lyapunov exponent [Formula see text] that quantifies the scrambling rate in chaotic systems obeys a universal bound [Formula see text]. Previous numerical and analytical studies have indicated that this bound has a quantum-statistical origin. Here, we use path-integral techniques to show that a minimal theory to reproduce this bound involves adding contributions from quantum thermal fluctuations (describing quantum tunneling and zero-point energy) to classical dynamics. By propagating a model quantum-Boltzmann-conserving classical dynamics for a system with a barrier, we show that the bound is controlled by the stability of thermal fluctuations around the barrier instanton (a delocalized structure which dominates the tunneling statistics). This stability requirement appears to be general, implying that there is a close relation between the formation of instantons, or related delocalized structures, and the imposition of the quantum-chaos bound.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Proc Natl Acad Sci U S A Año: 2023 Tipo del documento: Article País de afiliación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Proc Natl Acad Sci U S A Año: 2023 Tipo del documento: Article País de afiliación: Reino Unido