Your browser doesn't support javascript.
loading
Photoredox-Catalyzed Selective α-Scission of PR3-OH Radicals to Access Hydroalkylation of Alkenes.
Xie, Zhen-Zhen; Liao, Zi-Hao; Zheng, Yu; Yuan, Chu-Ping; Guan, Jian-Ping; Li, Ming-Zhi; Deng, Ke-Yi; Xiang, Hao-Yue; Chen, Kai; Yang, Hua.
Afiliación
  • Xie ZZ; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Liao ZH; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Zheng Y; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Yuan CP; School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, P. R. China.
  • Guan JP; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Li MZ; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Deng KY; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Xiang HY; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Chen K; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Yang H; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
Org Lett ; 25(50): 9014-9019, 2023 Dec 22.
Article en En | MEDLINE | ID: mdl-38063439
ABSTRACT
Photoinduced generation of phosphoranyl radicals offers a versatile strategy to access a variety of synthetically valuable radicals. A long-standing challenge remains in the regulation of phosphoranyl radical to undergo α-scission pathway, although the ß-scission mode has been intensively studied. We herein developed an unprecedented protocol for selective α-scission of the P(OH)R3 radical intermediate under photocatalytic conditions. This efficient P-C bond cleavage via α-scission of the P(OH)R3 radicals has been successfully utilized in the alkylation/fluoroalkylation of alkenes.
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2023 Tipo del documento: Article
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2023 Tipo del documento: Article