A visible-light-induced bromine radical initiates direct C-H alkylation of heteroaromatics.

Cao, Xiangxue; Wei, Lanfeng; Yang, Jinbo; Song, Huanhuan; Wei, Yu

Cao, Xiangxue; Wei, Lanfeng; Yang, Jinbo; Song, Huanhuan; Wei, Yu.

Afiliación

Cao X; School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi, 832003, China. yuweichem@shzu.edu.cn.
Wei L; Xinjiang Key Laboratory of Coal Mine Disaster Intelligent Prevention and Emergency Response, Xinjiang Institute of Engineering, Urumqi 830023, China. 1193631044@qq.com.
Yang J; School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi, 832003, China. yuweichem@shzu.edu.cn.
Song H; Bingtuan Energy Development Institute, Shihezi University, Shihezi, 832003, China. songhh@shzu.edu.cn.
Wei Y; School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi, 832003, China. yuweichem@shzu.edu.cn.

Org Biomol Chem ; 22(6): 1157-1161, 2024 Feb 07.

Article en En | MEDLINE | ID: mdl-38224149

ABSTRACT

ABSTRACT

Herein, a photoinduced direct C(sp2)-H alkylation of N-heteroaromatics by using commercially available tetrabutylammonium tribromide (TBATB) as a HAT reagent is described. The method uses O2 as the oxidant, and features metal-free, mild reaction conditions and good functional group compatibility.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

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