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Modulation of circularly polarized luminescence by swelling of microgels functionalized with enantiopure [Ru(bpy)3]2+ luminophores.
Yoshida, Kyohei; Kajiwara, Maino; Okazaki, Yutaka; Véronique, Lapeyre; Zinna, Francesco; Sojic, Neso; Bouffier, Laurent; Lacour, Jérôme; Ravaine, Valérie; Oda, Reiko.
Afiliación
  • Yoshida K; CNRS, Université de Bordeaux, Bordeaux INP, CBMN, UMR 5248, 33607, Pessac, France. reiko.oda@u-bordeaux.fr.
  • Kajiwara M; Kumamoto Industrial Research Institute, Materials Development Department, Kumamoto, JP 862-0901, Japan.
  • Okazaki Y; Department of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan.
  • Véronique L; Graduate School of Energy Science 3, Kyoto University, Yoshida-honmachi, Sakyo-ku, Kyoto 606-8501, Japan.
  • Zinna F; Univ. Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, F-33400 Talence, France.
  • Sojic N; Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland.
  • Bouffier L; Dipartimento di Chimica e Chimica Industriale, Università di Pisa Via Moruzzi 13, 56124 PISA, Italy.
  • Lacour J; Univ. Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, F-33400 Talence, France.
  • Ravaine V; Univ. Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, F-33400 Talence, France.
  • Oda R; Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland.
Chem Commun (Camb) ; 60(13): 1743-1746, 2024 Feb 08.
Article en En | MEDLINE | ID: mdl-38240695
ABSTRACT
Chemoresponsive microgels functionalized with enantiomeric Δ- or Λ-[Ru(bpy)3]2+ showed tunable chiroptical properties upon swelling and shrinking. The tuning is triggered by a modulation of the local mobility of [Ru(bpy)3]2+ upon addition of fructose, controlling interactions and distances between [Ru(bpy)3]2+ and phenylboronic acid.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Francia

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Francia