Visible light-induced hole transfer in single-nanoplate Cu1.81S-CdS heterostructures.

ABSTRACT

The separation and transfer of photogenerated carriers in semiconducting materials are essential processes that determine the efficiency of optoelectronic devices and photocatalysts, and transient absorption spectroscopy provides a powerful support for exploring the diffusion and recombination of photogenerated electrons and holes. Herein, high-quality Cu1.81S nanoplates were synthesized by a hot injection method, and were used as starting templates for the preparation of Cu1.81S-CdS heterojunctions and CdS nanoplates by cation exchange. Their carrier dynamics were investigated by transient absorption spectroscopy, which revealed that photogenerated holes may be transferred from the CdS phase to the Cu1.81S phase under 400 nm excitation. This process is in the opposite direction to the hole transfer induced by near-infrared localized surface plasmon resonance in copper sulfide heterostructures. Moreover, density functional theory calculations were used to further explain the visible light-induced hole transport process. This transfer is a potential way to increase the rate of H2 production and enhance the photostability of the catalyst.