Micropores in Hollow Organic Cage Nanocapsule as a Size Exclusion Gate: Cage Entrapped Pd(II)-Catalyst for Efficient Cross-Coupling Reaction.
Langmuir
; 40(17): 8820-8826, 2024 Apr 30.
Article
en En
| MEDLINE
| ID: mdl-38619546
ABSTRACT
Hollow porous organic capsules (HPOCs) with an entrapped active catalyst have nanosized cavities, providing the benefits of a nanoreactor, as well as separation of the catalysts from the reaction medium via pores acting as a size-exclusion gate. Such purpose-built HPOCs with desired molecular weight cutoffs offer the advantages of semipermeable membrane separation and a sustainable chemical process that excludes energy-extensive separation. Here, we report a newly synthesized HPOC with an entrapped Pd(PPh3)2Cl2 as the catalyst for demonstrating a Suzuki-Miyaura coupling reaction as a proof of concept.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Langmuir
Asunto de la revista:
QUIMICA
Año:
2024
Tipo del documento:
Article
País de afiliación:
India