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An extremely electron poor Au(III) trication bearing acetonitrile ligands.
Barwise, Lachlan; Moon, Lachlan J; Dhakal, Bibidh; Hogan, Conor F; White, Keith F; Dutton, Jason L.
Afiliación
  • Barwise L; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au.
  • Moon LJ; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au.
  • Dhakal B; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au.
  • Hogan CF; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au.
  • White KF; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au.
  • Dutton JL; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au.
Chem Commun (Camb) ; 60(43): 5586-5589, 2024 May 23.
Article en En | MEDLINE | ID: mdl-38699786
ABSTRACT
The synthesis and structural characterization of an electron poor Au(III) trication bearing 2 imidazole and 2 acetonitrile ligands is described. The new complex is capable of aryl C-H metalation with the formation of a monomesitylene complex and also demonstrated to be highly oxidizing in the rapid room temperature conversion of cyclohexene to benzene.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Reino Unido
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Reino Unido