Synthesis and properties of an <i>O</i>-doped aromatic belt.

Han, Ying; Guo, Wei-Chen; Du, Xu-Sheng; Chen, Chuan-Feng

Synthesis and properties of an O-doped aromatic belt.

Han, Ying; Guo, Wei-Chen; Du, Xu-Sheng; Chen, Chuan-Feng.

Afiliación

Han Y; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. hanying463@iccas.ac.cn.
Guo WC; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. hanying463@iccas.ac.cn.
Du XS; University of Chinese Academy of Sciences, Beijing 100049, China.
Chen CF; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. hanying463@iccas.ac.cn.

Chem Commun (Camb) ; 60(44): 5719-5722, 2024 May 28.

Article en En | MEDLINE | ID: mdl-38742271

ABSTRACT

ABSTRACT

A new macrocyclic arene, dibenzofuran[3]arene, was synthesized, which could be conveniently transformed to an O-doped aromatic belt with a rigid ring-shaped structure and deep cavity. Moreover, the O-doped aromatic belt also showed a high HOMO energy and a narrow HOMO-LUMO gap experimentally and theoretically.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

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