A sandwiched Co4-added polyoxometalate for efficient visible light-driven hydrogen evolution.

ABSTRACT

A new Co4-added polyoxometalate (CoAP) Cs4[(Co(H2O)5)2{(µ2-Co(H2O)4)2Co4(H2O)2(B-α-GeW9O34)2}]·6H2O (1) has been made using a lacunary directing strategy under hydrothermal conditions. Single-crystal X-ray diffraction analysis demonstrated that 1 is a one-dimensional (1D) chain, in which CoAP is linked by cobalt-oxygen octahedra to form a 1D structure with excellent chemical stability. The visible light-driven H2 evolution test demonstrated that 1 has high activity, with an H2 evolution rate of 1485.95 µmol h-1 g-1. PXRD and FT-IR tests demonstrated that compound 1 exhibits excellent heterogeneous catalytic stability.