Crystal structure and Hirshfeld surface of a penta-amine-copper(II) complex with urea and chloride.
Acta Crystallogr E Crystallogr Commun
; 80(Pt 6): 596-600, 2024 May 01.
Article
en En
| MEDLINE
| ID: mdl-38845712
ABSTRACT
The reaction of copper(II) oxalate and hexa-methyl-ene-tetra-mine in a deep eutectic solvent made of urea and choline chloride produced crystals of penta-amine-copper(II) dichloride-urea (1/1), [Cu(NH3)5]Cl2·CO(NH2)2, which was characterized by single-crystal X-ray diffraction. The complex contains discrete penta-amine-copper(II) units in a square-based pyramidal geometry. The overall structure of the multi-component crystal is dictated by hydrogen bonding between urea mol-ecules and amine H atoms with chloride anions.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr E Crystallogr Commun
Año:
2024
Tipo del documento:
Article
País de afiliación:
Irlanda
Pais de publicación:
ENGLAND
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ESCOCIA
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GB
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GREAT BRITAIN
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INGLATERRA
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REINO UNIDO
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SCOTLAND
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UK
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UNITED KINGDOM