Spectroscopic investigation, dielectric and antimicrobial properties of chitin-cellulose@ZnO/CuO conductive nanocomposites.

ABSTRACT

In this research, we fabricated a functional conductive nanocomposite with valuable properties through a chitin (CH) and cellulose (CE) polymerization process, incorporating ZnO/(0.1, 0.2, 0.3 mol.%) CuO bioactive nanoparticles. These bioactive nanoparticles, synthesized through sol-gel and polymerization interactions, greatly enhanced the structural, dielectric, and antimicrobial characteristics of CH-CE@ZnO/CuO conductive nanocomposites. The morphological analysis revealed that these nanoparticles, with diameters ranging from 11-25 nm, formed covalent bonds with the membrane matrix, bolstering the conductive nanocomposites ' structural integrity and dielectric performance. The dielectric properties of the conductive nanocomposites were significantly enhanced by the even distribution of ZnO/CuO nanoparticles within the CH-CE composite. Additionally, antimicrobial assessments demonstrated that the CH-CE@ZnO/CuO conductive nanocomposites displayed significant antibacterial properties against the Escherichia coli and Staphylococcus aureus, showcasing their potential as active packaging materials for electronic, biosensors, and sustainable applications.