Understanding the column and batch adsorption mechanism of pesticide 2,4,5-T utilizing alginate-biomass hydrogel capsule: A computational and economic investigation.

ABSTRACT

Water pollution has remained a pressing concern in recent years, presenting multifaceted challenges in search of effective mitigation strategies. Our study, which targets mitigating pollution caused by 2,4,5-trichlorophenoxyacetic acid (2,4,5-T), a significant aquatic pollutant, is innovative in its approach. We have identified adsorption as a promising, cost-effective method for its removal. Our research strategy involves dynamic adsorption utilizing a peristaltic pump and composite beads containing activated carbon and sodium alginate (CA/Alg), a novel combination that mimics industrial processes. To optimize column adsorption, we examine bead stability under varied pH conditions and optimize parameters such as concentration, adsorption time, and pH through batch adsorption experiments, employing experimental design techniques. Additionally, we optimize column adsorption factors, including bead height, circulation time, and flow rate, crucial for process efficiency, and under these optimum conditions (C2,4,5-T = 80 ppm. pH = 2, t = 27h30min, H = 30 cm and D = 0.5 mL/min) the capacity of adsorption equal to 748.25 mg/g. Characterization techniques like SEM, EDX, BET analysis, XRD, and FTIR provide insights into the morphology, composition, surface area (331 m2/g), pore volume (0.11 cm3/g), crystal structure, and functional groups of the CA-P/Alg adsorbent. Theoretical analysis elucidates the adsorption mechanism and interaction with pollutants. Economic analysis, encompassing CAPEX and OPEX estimation, evaluates the feasibility of implementing this cleanup method at an industrial scale, considering initial investment and ongoing operational costs, indicating potential savings of 64 % compared with the activated carbon normally used on the Moroccan market. This comprehensive and innovative approach addresses water pollution challenges effectively while ensuring economic viability for industry-scale implementation.