The denitrification characteristics of Na2S2O8 solution in a falling film reactor.
Environ Technol
; : 1-9, 2024 Jul 13.
Article
en En
| MEDLINE
| ID: mdl-39002156
ABSTRACT
Wet scrubbing technology is an effective emission control technology for marine diesel engines. Nitric oxide (NO) is one of the main component of ship emissions, the sodium persulfate (Na2S2O8) can facilitate the NO mass transfer process to a rapid reaction. Falling film reactors are widely used in rapid gas-liquid reactions, however, the reaction characteristics of denitrification using Na2S2O8 solution in a falling film reactor are not clear, which were investigated in this paper. The factors of NO mass transfer flux were tested with the liquid-gas ratio of 15 L/m3. The effects of solution properties and temperatures on the reaction driving force were studied by calculating the chemical reaction equilibrium constants and Gibbs free energy changes. The results showed that the NO mass transfer flux increased with the increase of temperature, Na2S2O8 concentration, O2 concentration and NO concentration. NO mass transfer flux increased by 41.00% and then decreased by 2.12% as the pH value increased from 7 to 10 and then rising to 12. The Gibbs free energy changes of alkaline solutions were 114.22%-130.99% lower than those of acidic solution at 303-343 K, and the chemical reaction equilibrium constants were higher. Na2S2O8/seawater system has great application potential in marine exhaust gas purification.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Environ Technol
Asunto de la revista:
SAUDE AMBIENTAL
/
TOXICOLOGIA
Año:
2024
Tipo del documento:
Article
Pais de publicación:
Reino Unido