Synthesis of a highly conductive coordination polymer film via a vapor-solid phase chemical conversion process.
Chem Commun (Camb)
; 60(66): 8720-8723, 2024 Aug 13.
Article
en En
| MEDLINE
| ID: mdl-39069836
ABSTRACT
A novel vapor-solid phase chemical conversion process is reported here to synthesise high-quality films of the conductive coordination polymer (c-CP) Ag5BHT (BHT = benzenehexanothiolate), which has the potential to be applied for the synthesis and processing of c-CP electronic devices. This approach involves reacting a silver oxide precursor and an H6BHT linker in an isopropanol solvent vapor atmosphere to obtain Ag5BHT thin films with controllable thickness (100-300 nm). The as-synthesized Ag5BHT thin films exhibit conductivities as high as 10 S cm-1. Additionally, under field-effect modulation, these nanofilms demonstrate remarkably high charge mobility (38 cm2 v-1 s-1).
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2024
Tipo del documento:
Article
País de afiliación:
China