Covalent Organic Frameworks for Photocatalytic Reduction of Carbon Dioxide: A Review.
ACS Nano
; 18(33): 21804-21835, 2024 Aug 20.
Article
en En
| MEDLINE
| ID: mdl-39116003
ABSTRACT
Covalent organic frameworks (COFs) are crystalline networks with extended backbones cross-linked by covalent bonds. Due to the semiconductive properties and variable metal coordinating sites, along with the rapid development in linkage chemistry, the utilization of COFs in photocatalytic CO2RR has attracted many scientists' interests. In this Review, we summarize the latest research progress on variable COFs for photocatalytic CO2 reduction. In the first part, we present the development of COF linkages that have been used in CO2RR, and we discuss four mechanisms including COFs as intrinsic photocatalysts, COFs with photosensitive motifs as photocatalysts, metalated COF photocatalysts, and COFs with semiconductors as heterojunction photocatalysts. Then, we summarize the principles of structural designs including functional building units and stacking mode exchange. Finally, the outlook and challenges have been provided. This Review is intended to give some guidance on the design and synthesis of diverse COFs with different linkages, various structures, and divergent stacking modes for the efficient photoreduction of CO2.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
ACS Nano
Año:
2024
Tipo del documento:
Article
País de afiliación:
China
Pais de publicación:
Estados Unidos