Recent developments in (bio)ethanol conversion to fuels and chemicals over heterogeneous catalysts.

ABSTRACT

Bioethanol is one of the most important bio-resources produced from biomass fermentation and is an environmentally friendly alternative to fossil-based fuels as it is regarded as renewable and clean. Bioethanol and its derivatives are used as feedstocks in petrochemical processes as well as fuel and fuel additives in motor vehicles to compensate for the depletion of fossil fuels. This review chronicles the recent developments in the catalytic conversion of ethanol to diethyl ether, ethylene, propylene, long-chain hydrocarbons, and other important products. Various heterogeneous catalysts, such as zeolites, metal oxides, heteropolyacids, mesoporous materials, and metal-organic frameworks, have been used in the ethanol conversion processes and are discussed extensively. The significance of various reaction parameters such as pressure, temperature, water content in the ethanol feed, and the effect of catalyst modification based on various kinds of literature are critically evaluated. Further, coke formation and coke product analysis using various analytical and spectroscopic techniques during the ethanol conversion are briefly discussed. The review concludes by providing insights into possible research paths pertaining to catalyst design aimed at enhancing the catalytic conversion of (bio)ethanol.