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Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes.
Jurt, Pascal; Gamboa-Carballo, Juan José; Schweinzer, Clara; Himmelbauer, Daniel; Thöny, Debora; Gianetti, Thomas L; Trincado, Monica; Grützmacher, Hansjörg.
Afiliación
  • Jurt P; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, CH-8049 Zurich, Switzerland. hgruetzmacher@ethz.ch.
  • Gamboa-Carballo JJ; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, CH-8049 Zurich, Switzerland. hgruetzmacher@ethz.ch.
  • Schweinzer C; Higher Institute of Technologies and Applied Sciences (InSTEC), University of Havana, Ave. S. Allende 1110, 10600 Havana, Cuba.
  • Himmelbauer D; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, CH-8049 Zurich, Switzerland. hgruetzmacher@ethz.ch.
  • Thöny D; Institute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163, A-1060 Vienna, Austria.
  • Gianetti TL; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, CH-8049 Zurich, Switzerland. hgruetzmacher@ethz.ch.
  • Trincado M; Department of Chemistry and Biochemistry, University of Arizona, University Blvd., Tucson, AZ 85719, USA. tgianetti@email.arizona.edu.
  • Grützmacher H; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, CH-8049 Zurich, Switzerland. hgruetzmacher@ethz.ch.
Dalton Trans ; 2024 Aug 14.
Article en En | MEDLINE | ID: mdl-39140315
ABSTRACT
This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Suiza
Texto completo
Añadir a Mi BVS
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Suiza