A scalable approach using a gC3N4-covalent organic framework hybrid catalyst towards sustainable hydrogen production from seawater and wastewater.

ABSTRACT

The photocatalytic generation of H2 using covalent organic frameworks (COFs) is gaining more interest. While numerous reports have focused on the production of H2 from deionized water using COFs, the inability to produce H2 from industrial wastewater or seawater is a common limitation in many reported catalysts. Additionally, many of these reports lack a clear path to scale up the catalyst synthesis. In this study, we explore the prospect of hybridizing a COF with gC3N4 to create a robust photocatalyst for efficient H2 generation. This hybrid exhibits outstanding performance not only in deionized water, but also in wastewater, and simulated seawater. Furthermore, we explore the feasibility of the bulk-scale synthesis and successfully produce a 20 g hybrid catalyst in a single batch, and the synthesis method is scalable to achieve the commercial target. Remarkably, a maximum HER rate of 94 873 µmol g-1 h-1 and 109 125 µmol g-1 h-1 was obtained for the hybrid catalyst from industrial wastewater and simulated seawater, respectively. The performance of bulk-scale batches closely matches that of the small-scale ones. This research paves the way for the utilization of organic photocatalysts on a commercial scale, offering a promising solution for sustainable large-scale H2 production.