Promoted production of Fe(IV)/Fe(V) intermediates in the calcium peroxide/ferrate(VI) process for low-damage removal of algal contaminants and membrane fouling control.

ABSTRACT

Ultrafiltration (UF) is widely employed for harmful algae rejection, whereas severe membrane fouling hampers its long-term operation. Herein, calcium peroxide (CaO2) and ferrate (Fe(VI)) were innovatively coupled for low-damage removal of algal contaminants and fouling control in the UF process. As a result, the terminal J/J0 increased from 0.13 to 0.66, with Rr and Rir respectively decreased by 96.74 % and 48.47 %. The cake layer filtration was significantly postponed, and pore blocking was reduced. The ζ-potential of algal foulants was weakened from -34.4 mV to -18.7 mV, and algal cells of 86.15 % were removed with flocs of 300 µm generated. The cell integrity was better remained in comparison to the Fe(VI) treatment, and Fe(IV)/Fe(V) was verified to be the dominant reactive species. The membrane fouling alleviation mechanisms could be attributed to the reduction of the fouling loads and the changes in the interfacial free energies. A membrane fouling prediction model was built based on a long short-term memory deep learning network, which predicted that the filtration volume at J/J0= 0.2 increased from 288 to 1400 mL. The results provide a new routine for controlling algal membrane fouling from the perspective of promoting the generation of Fe(IV)/Fe(V) intermediates.