Fe,Co co-implanted dendritic CeO2/CeF3 heterostructure@MXene nanocomposites as structurally stable electrocatalysts with ultralow overpotential for the alkaline oxygen evolution reaction.

ABSTRACT

Exploring low-cost, high-activity, and structurally stable nonprecious metal electrocatalysts for sluggish oxygen evolution reaction (OER) is paramount for water electrolysis. Herein, we successfully prepare a novel Fe,Co-CeO2/CeF3@MXene heterostructure with Fe-Co dual active sites and oxygen vacancies for alkaline OER using an energy-free consumption co-deposition method. Impressively, Fe,Co-CeO2/CeF3@MXene achieves an ultralow overpotential of 192 mV and a long-term stability of 110 h at 10 mA cm-2 without structural changes, thereby outperforming the commercial IrO2 (345 mV). In addition, Fe,Co-CeO2/CeF3@MXene exhibits much superior activity (271 mV) and durability to IrO2 (385 mV) in the real seawater OER. Wind- and solar energy-assisted water electrolysis devices show their promising prospects for sustainable green hydrogen production. Characterization techniques and theoretical calculations reveal that the Fe,Co co-implanted CeO2/CeF3 heterostructure effectively degrades the energy barrier of the OER and optimizes the adsorption strength of *OH, *O, and *OOH intermediates. It exhibits the dual coupling mechanism of the adsorbed evolution and lattice oxygen mechanisms, which synergistically improves the OER performance. This work provides a facile and efficacious strategy for synthesizing a new class of heterostructures to achieve significant enhancement in the activity and stability of OER catalysts.