Loading and thermal behaviour of ZIF-8 metal-organic framework-inorganic glass composites.
Dalton Trans
; 53(25): 10655-10665, 2024 Jun 25.
Article
in En
| MEDLINE
| ID: mdl-38860528
ABSTRACT
Here we describe the synthesis of a compositional series of metal-organic framework crystalline-inorganic glass composites (MOF-CIGCs) containing ZIF-8 and an inorganic phosphate glass, 20Na2O-10NaCl-70P2O5, to expand the library of host matrices for metal-organic frameworks. By careful selection of the inorganic glass component, a relatively high loading of ZIF-8 (70 wt%) was achieved, which is the active component of the composite. A Znâ¯O-P interfacial bond, previously identified in similar composites/hybrid blends, was suggested by analysis of the total scattering pair distribution function data. Additionally, CO2 and N2 sorption and variable-temperature PXRD experiments were performed to assess the composites' properties.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Dalton Trans
/
Dalton trans (2003. Online)
/
Dalton transactions (2003. Online)
Journal subject:
QUIMICA
Year:
2024
Document type:
Article
Country of publication: