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Molecular Editing of Pyrroles to Benzenes/Naphthalenes by N2O Deletion.
Xiao, Wen-Jie; Li, Cheng-Xin; Lv, Jing-Yi; Xu, Shan; Shi, Wen-Xia; Su, Xiao-Can; Xue, Jia-Ying; Huang, Bao-Qin; Zou, Yong; Yan, Ming; Zhang, Xue-Jing.
Affiliation
  • Xiao WJ; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Li CX; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Lv JY; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Xu S; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Shi WX; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Su XC; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Xue JY; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Huang BQ; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Zou Y; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Yan M; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
  • Zhang XJ; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China.
Angew Chem Int Ed Engl ; 63(43): e202411166, 2024 Oct 21.
Article in De | MEDLINE | ID: mdl-39008335
ABSTRACT
A molecular editing reaction for converting pyrrole rings into benzene rings through a sequential pathway of Diels-Alder and cheletropic reactions was developed. The nitrogen atom in a N-bridged intermediate is eliminated in the form of N2O by a strain-releasing pathway, ultimately leading to the formation of substituted benzene and naphthalene derivatives.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: De Journal: Angew Chem Int Ed Engl / Angew. Chem. (Int. ed., Internet) / Angewandte Chemie (International ed. Internet) Year: 2024 Document type: Article Affiliation country: Country of publication:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: De Journal: Angew Chem Int Ed Engl / Angew. Chem. (Int. ed., Internet) / Angewandte Chemie (International ed. Internet) Year: 2024 Document type: Article Affiliation country: Country of publication: