Locked pi-expanded chlorins in two steps from simple tetraarylporphyrins.
Org Lett
; 7(23): 5257-60, 2005 Nov 10.
Article
de En
| MEDLINE
| ID: mdl-16268552
ABSTRACT
[reaction see text] Upon tandem Reformatsky reaction, easily accessible porphyrinic ketones give "locked" chlorinic diester. Both ketones and diesters, as bases or palladium complexes, efficiently generate singlet dioxygen, as demonstrated by trapping with cholesterol.
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Collection:
01-internacional
Base de données:
MEDLINE
Langue:
En
Journal:
Org Lett
Sujet du journal:
BIOQUIMICA
Année:
2005
Type de document:
Article
Pays d'affiliation:
France