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An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions.
Axe, Philip; Bull, Steven D; Davidson, Matthew G; Jones, Matthew D; Robinson, Diane E J E; Mitchell, William L; Warren, John E.
Affiliation
  • Axe P; Department of Chemistry, University of Bath, UK BA2 7AY.
Dalton Trans ; (46): 10169-71, 2009 Dec 14.
Article de En | MEDLINE | ID: mdl-19921048
ABSTRACT
A chiral pseudo-C(3)-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.
Sujet(s)

Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Sujet principal: Sulfoxydes / Titane / Méthanesulfonates Langue: En Journal: Dalton Trans Sujet du journal: QUIMICA Année: 2009 Type de document: Article

Texte intégral: 1 Collection: 01-internacional Base de données: MEDLINE Sujet principal: Sulfoxydes / Titane / Méthanesulfonates Langue: En Journal: Dalton Trans Sujet du journal: QUIMICA Année: 2009 Type de document: Article