Alkenyl/thiol-derived metal-organic frameworks (MOFs) by means of postsynthetic modification for effective mercury adsorption.
Chemistry
; 20(43): 14090-5, 2014 Oct 20.
Article
de En
| MEDLINE
| ID: mdl-25210002
ABSTRACT
The synthesis of new functionally diverse alkenyl-derived Cr-MIL-101s (MIL=material of Institute Lavoisier) was realized by a novel and convenient postsynthetic modification (PSM) protocol by means of the carbon-carbon bond-forming Mizoroki-Heck reaction. The new PSM protocol demonstrates a broad scope of substrates with excellent tolerance of functionality under mild reaction conditions. Moreover, a new metal-organic framework (MOF) that bears both alkenyl and thiol side chains prepared by means of the tandem PSM method has shown excellent adsorbent ability in removing mercury ions from water.
Mots clés
Texte intégral:
1
Collection:
01-internacional
Base de données:
MEDLINE
Sujet principal:
Composés organométalliques
/
Thiols
/
Polluants de l'eau
/
Chrome
/
Alcènes
/
Mercure
Langue:
En
Journal:
Chemistry
Sujet du journal:
QUIMICA
Année:
2014
Type de document:
Article